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Физическая химия Физическая химия

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Self-Assembly of Oppositely Charged Polyoxometalate Nanoclusters, Nanoparticles. Various Crystal Structures of Polyoxometalate Anions - Keggin Type Aluminum Cations and Oppositely Charged Colloidal Silica-polymer Sphere System

Автор:
мягкая обложка
108 страниц
2008 год
Издательство:  Книга по Требованию
Цена:
1994 руб
отсутсвует
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Описание:Their polyhedral shapes results in interesting molecular packing scheme. The idea is to get nanocomposite from ionic interaction between polyoxometalate anions (Mo7, AlMo6, W12, V2W4) and aluminum cations (Al13, Al30). The structural determinations show that hydrogen bonding and Coulombic force dominate the intercluster interactions. Al13-2AlMo6 crystals demonstrate reversible and selective adsorption of water in their pores. Also included are 1) self-assembly of oppositely charged silica or polymer spheres with different sizes, 2) nickel fine particle synthesis for MLCC application, 3) surface modification or coating of inverse opal carbon materials with polyoxometalate or metal. And packing of nanometer size clusters leads to the formation of large pores, which could be utilized to sorptive materials or catalysts. Their self assembly in aqueous solution produced solid nanocomposite material in the form of single crystals or gels. Single crystals of Al13-2AlMo6, Al13-W12, Al13-2V2W4, W2Al28-2W12 has been fully characterized. This book covers a comprehensive study on the new-concept inorganic nanocomposite materials.


Orthomol Immun Junior Сила иммунитета на страже Вашего ребенка Orthomol Immun Junior Сила иммунитета на страже Вашего ребенка

2990 руб
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A short history of nearly everything

Thorne, Alan Thorne, Kip S. Thorstensen, John time, general theory of relativity and TimeБЂ™s Arrow (Gould) tin titanium Titans of the Deep (film) Tombaugh, Clyde Trans-Neptunian Objects Trefil, James triangulation. trilobites, Trinkaus, Erik Tryon, Edward P. tsunami Tsurutani, Bruce Turkana, Lake, Kenya U ulcers Uncertainty Principle U.S. Naval Observatory, Flagstaff, Arizona universe: age of; birth of (Big Bang theory); cosmic background radiation; curvature of space; dark energy (vacuum energy, quintessence); dark matter; edge of; emptiness of; end of; expanding; Goldilocks effect; gravity in; inflation theory; ordered self-assembly in; parsec (vs. light-years); planets in, number of; planets, life-sustaining; theory of many universes; size of; visible uranium; decay rate into lead Uranus Urey, Harold Ussher, James V Valц©ry, Paul Varuna Venus: conditions on; lack of tectonic activity; transits of Vermeer, Jan Vestiges of the Natural History of Creation (Chambers) Vine, Fred viruses Vogel, Shawna volcanoes: Ashfall Fossil Beds, Nebraska, and; Bruneau-Jarbidge, Idaho; climatic consequences,; Deccan Traps; Galeras, Colombia; caldera; hypertrophic pulmonary osteodystrophy; Krakatau, Indonesia; lack of preparedness; predicting; pyroclastic flow; St ...»

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